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Kinetics of reaction of benzyl chloride with H2S-rich aqueous monoethanolamine: selective synthesis of dibenzyl sulfide under liquid–liquid phase-transfer catalysis

✍ Scribed by Sujit Sen; Narayan C. Pradhan; Anand V. Patwardhan

Publisher
Wiley (John Wiley & Sons)
Year
2011
Tongue
English
Weight
350 KB
Volume
6
Category
Article
ISSN
1932-2135

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Reaction of benzyl chloride with ammonium sulfide under liquid–liquid phase transfer catalysis: Reaction mechanism and kinetics
✍ Sunil K. Maity; Narayan C. Pradhan; Anand V. Patwardhan 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 610 KB

The reaction between benzyl chloride and aqueous ammonium sulfide was carried out in an organic solvent -toluene, using tetrabutylammonium bromide (TBAB) as phase transfer catalyst (PTC). Two products, namely dibenzyl sulfide (DBS) and benzyl mercaptan (BM), were identified in the reaction mixture.