The kinetics of four gas-phase reactions involving halogenated methyl radicals (R,==CF,, CF2C1, CFCI,, and eel,) with molecular chlorine have been studied using a tuhular reactor coupled to a photoionization mass spectrometer. The radicals were homogeneously generated by the pulsed photolysis of pre
Kinetics of the reactions of halogenated methyl radicals with molecular bromine
β Scribed by Timonen, R. S.; Seetula, J. A.; Niiranen, J.; Gutman, D.
- Book ID
- 121184478
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 710 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
Br2 reaction has been mranued at room temperature in two discharge-tlo\\ \) stems u~ng whrr electron p~mmssneuc rcsommce or laser-induced fluorescence for OH analysis The result is R = (4 12 0.7) x 10-11 cm3 molrcule-1 s-' \_ The measurement of the Br J ield produced in this reaction indicates that
## Abstract The reaction of methyl radicals with atomic and molecular oxygen was studied with a photoionization mass spectrometer. The methyl radicals were generated by reacting oxygen atoms with ethylene in a fastβflow tube reactor. The rate constant for the reaction of methyl radicals with oxygen