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Kinetics of the Reactions of Allyl and Propargyl Radicals with CH 3

✍ Scribed by Knyazev, Vadim D.; Slagle, Irene R.

Book ID
125985576
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
99 KB
Volume
105
Category
Article
ISSN
1089-5639

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Propargyl (HC#C 9 CH 2 ) and methyl radicals were produced through the 193-nm excimer laser photolysis of mixtures of C 3 H 3 Cl/He and CH 3 N 2 CH 3 /He, respectively. Gas chromatographic and mass spectrometric (GC/MS) product analyses were employed to characterize and quantify the major reaction p