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Kinetics of the reaction of the sulfate radical with the oxalate anion

✍ Scribed by Robert E. Huie; Carol L. Clifton

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 321 KB
Volume: 28
Category: Article
ISSN: 0538-8066
DOI: 10.1002/(sici)1097-4601(1996)28:3<195::aid-kin5>3.0.co;2-q

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✦ Synopsis

The kinetics of the reaction of the sulfate radical, SO4-. with the oxalate anion, CzOz-, was studied in aqueous solution and second-order rate constants, corrected for the effects of ionic strength, derived Measurements were carried out over the temperature range 24-60°C resulting in the expression ko = 2.10 t 0.96 X lo8 exp(-1080 +.

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