✦ LIBER ✦

Kinetics of the reaction of benzoyl chloride and sodium carboxylate under inverse phase-transfer catalysis

✍ Scribed by Maw-Ling Wang; Chin-Chou Ou; Jing-Jer Jwo

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 719 KB
Volume: 99
Category: Article
ISSN: 1381-1169
DOI: 10.1016/1381-1169(95)00006-2

No coin nor oath required. For personal study only.

✦ Synopsis

The reaction of benzoyl chloride and sodium carboxylate using pyridine 1 -oxide (PNO) as an inverse phase-transfer catalyst in a system of the two phases HZ0 and CH&& was investigated. Carboxylate ions including formate, acetate, propionate, 2methylpropanoate, pentanoate, hexanoate, heptanoate and octanoate were selected to compare their reactivities. The rate of reaction depended on the concentration of pyridine l-oxide (PNO) in the organic phase. The concentration of carboxylate ion affected the distribution of pyridine 1 -oxide (PNO) between the organic and aqueous phases. The rate of reaction thus depended on the concentration of the carboxylate ion even though the rate-determining step occurred in the organic phase.

📜 SIMILAR VOLUMES

Inverse phase transfer catalysis: kineti

Inverse phase transfer catalysis: kinetics of the pyridine 1-oxide-catalyzed two-phase reactions of fluoro- and butyl-benzoyl chlorides and benzoate ions

✍ Shu-Mei Hung; Jing-Jer Jwo 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 166 KB

ChemInform Abstract: Synthesis of Sodium

ChemInform Abstract: Synthesis of Sodium Diselenide under Phase Transfer Catalysis and Microwave Irradiation Conditions and Its Reaction with Benzoyl Chloride.

✍ Jin-Xian Wang; Lin Bai; Zhanxiang Liu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 27 KB 👁 2 views

Inverse phase transfer catalysis: kineti

Inverse phase transfer catalysis: kinetics of the pyridine-1-oxide-catalyzed two-phase reactions of methyl-, methoxy-, iodo-, and nitro-benzoyl chlorides and benzoate ions

✍ Yen Liang Lu; Jing-Jer Jwo 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 136 KB

Reaction of benzyl chloride with ammoniu

Reaction of benzyl chloride with ammonium sulfide under liquid–liquid phase transfer catalysis: Reaction mechanism and kinetics

✍ Sunil K. Maity; Narayan C. Pradhan; Anand V. Patwardhan 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 610 KB

The reaction between benzyl chloride and aqueous ammonium sulfide was carried out in an organic solvent -toluene, using tetrabutylammonium bromide (TBAB) as phase transfer catalyst (PTC). Two products, namely dibenzyl sulfide (DBS) and benzyl mercaptan (BM), were identified in the reaction mixture.

Inverse phase transfer catalysis. Kineti

Inverse phase transfer catalysis. Kinetics of the pyridine 1-oxide-catalyzed reactions of dichlorobenzoyl chlorides and benzoate ions

✍ Yung Sheng Chang; Jing-Jer Jwo 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 229 KB

Kinetics of reaction of benzyl chloride

Kinetics of reaction of benzyl chloride with H2S-rich aqueous monoethanolamine: selective synthesis of dibenzyl sulfide under liquid–liquid phase-transfer catalysis

✍ Sujit Sen; Narayan C. Pradhan; Anand V. Patwardhan 📂 Article 📅 2011 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 350 KB