The cherniluminescence in the H+ 0, -OH(X \*lIIW,& +O, reaction was observed uvng a crossed beam tcebnlqu& l%e tnilial population of the OH radicals tn the vibratIonal slate v (4 < u UG 9) were found to be N( 9) -1.0, N(B) -0.95&O 1, N(7) -0.9kO.2, N(6) -0 2\*0 1 and N(5) -N(4) -0 2&O 2 The IOEII cr
Kinetics of the Radical−Radical Reaction, O( 3 P J ) + OH(X 2 Π Ω ) → O 2 + H, at Temperatures down to 39 K †
✍ Scribed by Carty, David; Goddard, Andrew; Köhler, Sven P. K.; Sims, Ian R.; Smith, Ian W. M.
- Book ID
- 126899137
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 113 KB
- Volume
- 110
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Rate constants for the reactions of 0 3 and OH radicals with furan and thiophene have been determined at 298 f 2 K. The rate constants obtained for the 0 3 reactions were (2.42 f 0.28) X 1O-lS cm3/molec.s for furan and <6 X cm3/molec-s for thiophene. The rate constants for the OH radical reactions,
The kinetics of the gas-phase reactions of the OH radical with (C,H,O),PO and (CH30)2P(S)C1 and of the reactions of NO, radicals and O3 with (CH,O),P(S)Cl have been studied at room temperature. Using a relative rate technique, the rate constants determined for the reactions of the OH radical with (C
The kinetics of the gas-phase reactions of naphthalene, 2-methylnaphthalene, and 2,3-dimethylnaphthalene with O3 and with OH radicals have been studied at 295 L 1 K in one atmosphere of air. Upper limit rate constants for the O3 reactions of <3 x lo-", , : 4 x lo-", and <4 x lo-'' cm3 molecule-' s-'