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Kinetics of the primary interaction of pentacyanonitrosylferrate(2-) (nitroprusside) with aliphatic thiols

✍ Scribed by Johnson, Michael D.; Wilkins, Ralph G.

Book ID
120182593
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
605 KB
Volume
23
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

The reaction of pentacyanonitrosylferrat
The reaction of pentacyanonitrosylferrate(II) with primary amines as a source of stabilized aliphatic diazonium ions: a new route to secondary amines
✍ Fabio Doctorovich; Cecilia TrΓ‘pani πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 302 KB

Pentacyanonitrosylferrate(II), 1, reacts with n-butylamine to produce di-n-butylamine in high yields (81-95%). The absence of rearranged products indicates that the initially produced diazonium ion is stabilized by coordination to the metal. Benzylamine and 1,4-diaminobutane react with 1 to produce