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Kinetics of the permanganate-bromide reaction at low reagent concentrations

โœ Scribed by Lawani, Samuel A.

Book ID
118002817
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
321 KB
Volume
80
Category
Article
ISSN
0022-3654

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Kinetics of the bromateโ€“bromide reaction
Kinetics of the bromateโ€“bromide reaction at high bromide concentrations
โœ Guy Schmitz ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 216 KB

## Abstract At bromide concentrations higher than 0.1 M, a second term must be added to the classical rate law of the bromateโ€“bromide reaction that becomes โˆ’d[BrO~3~^โˆ’^]/d__t__ = [BrO~3~^โˆ’^][H^+^]^2^(__k__~1~[Br^โˆ’^] + __k__~2~[Br^โˆ’^]^2^). In perchloric solutions at 25ยฐC, __k__~1~ = 2.18 dm^3^ mol^โˆ’