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Kinetics of the OH-initiated oxidation of isoprene

✍ Scribed by Campuzano-Jost, Pedro; Williams, Margaret B.; O'Ottone, Luca; Hynes, Anthony J.


Book ID
119652876
Publisher
American Geophysical Union
Year
2000
Tongue
English
Weight
515 KB
Volume
27
Category
Article
ISSN
1944-8007

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## Abstract The kinetics of the recombination reaction, OH+NO+(M) β†’ Products have been investigated by the Pulsed Laser Photolysis‐Laser Induced Fluorescence (PLP‐LIF) technique in nitrogen and helium buffer gases at room temperature and as a function of pressure (30‐900 Torr). Our values for the a

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## Abstract Rate constants for several intermediate steps in the OH‐initiated oxidation of isoprene were determined using laser‐photolysis/laser‐induced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K. The rate constant for decomposition of the hydroxyalkoxy radical was