Kinetics of the OH-initiated oxidation of isoprene
β Scribed by Campuzano-Jost, Pedro; Williams, Margaret B.; O'Ottone, Luca; Hynes, Anthony J.
- Book ID
- 119652876
- Publisher
- American Geophysical Union
- Year
- 2000
- Tongue
- English
- Weight
- 515 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1944-8007
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## Οͺ12 Οͺ1 Οͺ1 9 Ο« 10 mol s of 2) for the reaction of isoprene-based hydroxyalkyl peroxy radicals with NO.
## Abstract The kinetics of the recombination reaction, OH+NO+(M) β Products have been investigated by the Pulsed Laser PhotolysisβLaser Induced Fluorescence (PLPβLIF) technique in nitrogen and helium buffer gases at room temperature and as a function of pressure (30β900 Torr). Our values for the a
## Abstract Rate constants for several intermediate steps in the OHβinitiated oxidation of isoprene were determined using laserβphotolysis/laserβinduced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K. The rate constant for decomposition of the hydroxyalkoxy radical was