ESR spectra of o-semiquinone radicals produced by dnect photolysis of pyrocatechol in various solvents are reported. In aprotic. neutral solvents the kinetic effects in the ESR spectra reflect the dynamics of the intramolecular hydrosen hond, %hich is superimposed by intermolecular processes in the
β¦ LIBER β¦
Kinetics of the interaction of ketyl and semiquinone radicals with dioxygen. Concerted electron and proton transfer involving ketyl and semiquinone radicals
β Scribed by A. S. Tatikolov
- Publisher
- Springer
- Year
- 1997
- Tongue
- English
- Weight
- 605 KB
- Volume
- 46
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Effects of intramolecular and intermolec
β
K. Loth; F. Graf; Hs.H. GΓΌnthard
π
Article
π
1977
π
Elsevier Science
π
English
β 521 KB
Structures of ionic species and electron
β
S.W. Mao; N. Hirota
π
Article
π
1973
π
Elsevier Science
π
English
β 283 KB
EPR and optical spectra of magnesium and calcium kc:y!s were investigated in hlTHF and mixtures of DXIF and MTHF at various concentrations. It was shown that these ketyls form aggregates in ethereal solvents and dissociate into biradicals in mcrc polar solutions. hfodcls of ion aggregate to explcin
O-H bond dissociation energies in hydroq
β
V. T. Varlamov; B. E. Krisyuk; A. V. Antonov
π
Article
π
2005
π
Springer
π
English
β 456 KB
Effect of solvation on the kinetic param
β
V. T. Varlamov; B. E. Krisyuk
π
Article
π
2006
π
Springer
π
English
β 452 KB
Direct EPR Detection of a Hydrogen-Bonde
β
Junpei Yuasa; Shunsuke Yamada; Shunichi Fukuzumi
π
Article
π
2007
π
John Wiley and Sons
π
English
β 186 KB
π 2 views
Direct EPR Detection of a Hydrogen-Bonde
β
Junpei Yuasa; Shunsuke Yamada; Shunichi Fukuzumi
π
Article
π
2007
π
John Wiley and Sons
π
English
β 186 KB
π 2 views