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Kinetics of the initiation of styrene polymerization by n-butyllithium

โœ Scribed by O'driscoll, K. F. ;Ricchezza, E. N. ;Clark, J. E.

Publisher
Wiley (John Wiley & Sons)
Year
1965
Tongue
English
Weight
430 KB
Volume
3
Category
Article
ISSN
0449-2951

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## Abstract The polymerization of styrene by __n__โ€butyllithium and titanium tetrachloride has been examined. Isotactic polystyrene is obtained only when 3.00 > __n__โ€BuLi/TiCl~4~ > 1.75. At ratios less than 1.75 and greater than 3.00 only amorphous polystyrene (soluble in MEK) was formed. The mole

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The polymerization of styrene catalyzed by n-butyllithium has been carried out in the presence of carbon black at 0ยฐC in toluene. A large portion of the catalyst was consumed by the reaction with the carbon black surface and thus the growth of polystyrene anions on the surface was hindered to a cons