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The kinetics of the polymerization of styrene initiated by n-butyl lithium

✍ Scribed by R.C.P. Cubbon; D. Margerison

Publisher
Elsevier Science
Year
1965
Tongue
English
Weight
227 KB
Volume
6
Category
Article
ISSN
0032-3861

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πŸ“œ SIMILAR VOLUMES

The polymerization of substituted styren
The polymerization of substituted styrenes by butyl lithiumβ€”I. The initiation reaction
✍ G.M. Burnett; R.N. Young πŸ“‚ Article πŸ“… 1966 πŸ› Elsevier Science 🌐 English βš– 421 KB

The initiation of some substituted styrenes by butyl lithium has been studied. In hydrocarbon solvents the rates are given byRi ~k [M][BuLi] n where n lies between ΒΌ and ~ for benzene solutions and is approximately 0.57 for n-hexane solution. In benzene solution the relative rates of initiation of t

Radical polymerization of styrene initia
Radical polymerization of styrene initiated by benzopinacolates: kinetics and comments concerning the reaction mechanism
✍ Ramiro Guerrero Santos; Philippe R. Chaumont; Jean E. Herz; Gerard J. Beinert πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 716 KB

A~tract--The present paper reports an investigation on the "pseudo-living'" radical chain propagation process in the case of the styrene polymerization initiated by benzopinacolates. Two steps were observed, as in earlier reported investigations. Oligomers were formed first at low monomer conversion