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Kinetics of the hydrolysis of aquopentaamminecobalt(III) and diaquotetraamminecobalt(III) cations in aqueous perchloric acid

✍ Scribed by William D. Stanley; Silas Lum; Clifford S. Garner

Book ID: 118909770
Publisher: Elsevier Science
Year: 1973
Weight: 461 KB
Volume: 35
Category: Article
ISSN: 0022-1902
DOI: 10.1016/0022-1902(73)80369-0

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The Co(NH3) 50Hz3+ ion reacts with malonate to form Co(NH3) 50~CCH2C02H2+ or Co(NH3) 50ZCCHzCOz+, depending on the pH of the reaction solution. The kinetics of this anation reaction have been studied as a function of [H+] for the acidity range 1.5 5 pH 5 6.0 in the temperature range of 60 to 8OoC, t