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Kinetics of the Homogeneous Catalytic Hydroformylation of 1-Octene in Supercritical Carbon Dioxide with HRh(CO)[P( p -CF 3 C 6 H 4 ) 3 ] 3

✍ Scribed by Palo, Daniel R.; Erkey, Can


Book ID
126069724
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
81 KB
Volume
38
Category
Article
ISSN
0888-5885

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## Abstract Rhodium complexes of formula [RhBp(CO)P] [Bp = bis(pyrazolylborate), P = P(NC~4~H~4~)~3~ 1, PPh~3~ 2, PCy~3~ 3, P(C~6~H~4~OMe‐4)~3~ 4] have been prepared by exchange of the acetylacetonate (acac^βˆ’^) ligand in [Rh(acac)(CO)P] complexes. The spectroscopic and electrochemical properties as