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Kinetics of the high-temperature thermal decomposition of silanes and alkylsilanes

โœ Scribed by Ring, M. A.; O'Neal, H. E.; Rickborn, S. F.; Sawrey, B. A.

Book ID
127112862
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
488 KB
Volume
2
Category
Article
ISSN
0276-7333

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The homogeneous gas-phase decomposition kinetics of silane has been investigated using the single-pulse shock tube comparative rate technique (T = 1035-1184ยฐK, P ~d = 4000 Torr). The initial reaction of the decomposition SiH4 ! + SiHz + H2 is a unimolecular process in its pressure fall-off regime w