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Kinetics of the gas-phase thermal bromination of acetone. Heat of formation and stabilization energy of the acetonyl radical

✍ Scribed by King, Keith D.; Golden, David M.; Benson, Sidney W.


Book ID
126842259
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
631 KB
Volume
92
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Kinetics of the gas-phase reaction of ac
✍ R. K. Solly; D. M. Golden; S. W. Benson πŸ“‚ Article πŸ“… 1970 πŸ› John Wiley and Sons 🌐 English βš– 525 KB

The kinetics of the gas-phase reaction CH,COCH, + I, + CH,COCH,I + HI have been measured spectrophotometrically in a static system over the temperature range 340-430Β°. The pressure of CH,COCH, was varied from 15 to 330 torr and of I, from 4 to 48 torr, and the initial rate of the reaction was found

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## Abstract The decomposition of acetonyl bromide, isopropenylmethylether, and hexanedione‐2,5 was studied using the very‐low‐pressure pyrolysis (VLPP) technique. The acetonyl radical is a product of each reaction. Arrhenius parameters determined are or acetonyl bromide ← acetonyl + Br: and for i

Kinetics of the gas-phase reaction of al
✍ Ze'ev B. Alfassi; David M. Golden πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 430 KB πŸ‘ 1 views

## Abstract The reaction of iodine with allyl alcohol has been studied in a static system, following the absorption of visible light by iodine, in the temperature range 150‐190Β°C and in the pressure range 10‐200 torr. The rate‐determining step has been found to be equation image and __k__~3~ is c

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✍ Donald F. McMillen; David M. Golden; Sidney W. Benson πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 721 KB

The rate of the gas phase reaction A-CH,-I + I . 5 A-CH~. + I, has been measured spectrophotometrically over the range 480Β°-5500K. fits the equation log k (M-l sec-l) = 11.4 f 0.1 -(16.8 i 0.2)/8 where e = 2.303RT in kcal/mole. This result, together with the assumption that the activation energy fo