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Kinetics of the gas-phase reaction of benzaldehyde with iodine. Heat of formation and stabilization energy of the benzoyl radical

✍ Scribed by Solly, Richard K.; Benson, Sidney W.


Book ID
126873127
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
488 KB
Volume
93
Category
Article
ISSN
0002-7863

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The kinetics of the gas-phase reaction CH,COCH, + I, + CH,COCH,I + HI have been measured spectrophotometrically in a static system over the temperature range 340-430Β°. The pressure of CH,COCH, was varied from 15 to 330 torr and of I, from 4 to 48 torr, and the initial rate of the reaction was found

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## Abstract The reaction of iodine with allyl alcohol has been studied in a static system, following the absorption of visible light by iodine, in the temperature range 150‐190Β°C and in the pressure range 10‐200 torr. The rate‐determining step has been found to be equation image and __k__~3~ is c

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The rate of the gas phase reaction A-CH,-I + I . 5 A-CH~. + I, has been measured spectrophotometrically over the range 480Β°-5500K. fits the equation log k (M-l sec-l) = 11.4 f 0.1 -(16.8 i 0.2)/8 where e = 2.303RT in kcal/mole. This result, together with the assumption that the activation energy fo

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## Abstract The gas phase reaction of iodine (2.8–43.3 torr) with methyl ethyl ketone (MEK) (7.4–303.4 torr) has been studied over the temperature range 280–355Β°C in a static system. The initial rate of disappearance of I~2~ is first order in MEK and half order in I~2~. The rate‐determining step is