The temperature dependence of emission spectra and their decay parameters for pyromellitic dianhydride-phenanthrene chargetransfer crystals have been investigated between 1.7 and 300 K. It has been established that the delayed fluorescence originates from triplet-triplet annihilation at temperatures
Kinetics of the emission in the charge-transfer crystal of pyromellitic dianhydride-phenanthrene
β Scribed by B. Kozankiewicz
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 397 KB
- Volume
- 160
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The temperature dependence of fluorescence, phosphorescence and delayed fluorescence intensities and decay times were studied for the charge-transfer crystal of pyromellitic dianhydride-phenanthrene, between 5 and 300 K. A kinetic model which describes the behaviour of emission of this crystal is proposed. The temperature-dependent rate of deactivation of singlet excitons is discussed.
π SIMILAR VOLUMES
Singlet and triplet exciton energy migration in the charge-transfer crystal of pyromellitie dianhydride-phenanthrene, undoped and doped with anthracene (10-4-10-2 M/M), have been studied in the 5-300 K temperature range. At low temperatures singlet and triplet excitons are self-trapped. They become
Thermal-delayed fluorescence of pyromellitic dianhydride
High resolution speclrn of the 1:l CT-crystal anthracene-pyromelljric-ni-id-di3nhydride (A.PLIDA) show nt low tcmperatures sharp structures in absorprion and in emission. We attribute these structures to a zero-phonon transition which is accompanied by vibronic satellites. The spectra yield the coup