Kinetics of t-caprolactone (tCL) polymerization initiated with diethylaluminum ethoxide in benzene (C6H6) and acetonitrile (CH3CN) as solvents was studied and compared with the previously studied polymerization conducted in tetrahydrofuran (THF) solvent. Kinetic data were analyzed in terms of the ki
Kinetics of the Dispersion Ring-Opening Polymerization of ε-Caprolactone Initiated with Diethylaluminum Ethoxide
✍ Scribed by Gadzinowski, Mariusz; Sosnowski, Stanislaw; Slomkowski, Stanislaw
- Book ID
- 126115984
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 214 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0024-9297
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Polymerization of 1-caprolactone had been investigated with cyclopentadienyl sodium as an initiator. The effects of reaction time, temperature, and concentration of the initiator on the yield and molecular weight of the polymer were discussed. It was shown that the high molecular weight of poly(1-ca
A novel 5'-deoxy-5-fluorouridine-poly(epsilon-caprolactone) (5'-DFUR-PCL) polymer was synthesized from the antitumor agent doxifluridine (5'-DFUR) by the ring-opening polymerization of epsilon-caprolactone (epsilon-CL) using Sn(II) 2-ethylhexanoate (Sn(Oct)2) as the catalyst. The structure and molec