Kinetics of the decomposition of iodine amine in liquid ammonia
✍ Scribed by R. Kerbachi; R. Minkwitz; U. Engelhardt
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 169 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0020-1693
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The ratc of disappearance of solvated electrons by reaction with fluorobcnzcne in ammonia is acce!erated by smal1 conccntrations of methanol; it also bas a "negative activation energy" depending on the methanol concentration. The kinetic dota suggest an csothermic electron attachment-detachment equi
## Abstract 5‐ and 6‐Nitroquinoxalines and some of their derivatives are aminated in a liquid ammonia solution of potassium permanganate to yield the corresponding 2‐ and/or 3‐ and/or 5‐amino compounds. Quantum‐chemical calculations are made to explain the regioselectivity of the amination reaction
## Abstract 5‐ and 8‐Nitroisoquinoline and some of their derivatives are aminated in a liquid ammonia solution of potassium permanganate to yield the corresponding 6‐ and 7‐amino compounds. From 5,7‐dinitroisoquinoline the 6,8‐diamino derivative is obtained; 1‐nitroisoquinoline has been found to be