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Kinetics of the competitive 1,2-carbon migrations of an unsymmetrically substituted cyclopropylchlorocarbene

โœ Scribed by Moss, Robert A.; Liu, Weiguo; Krogh-Jespersen, Karsten


Book ID
121435586
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
743 KB
Volume
97
Category
Article
ISSN
0022-3654

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Competitive kinetics of 1,2-carbon and h
โœ Robert A. Moss; Ho Guo-Jie ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 233 KB

Cyclobutylchlorocarbene undergoes competitive 1,2-carbon and 1,2-hydride intramoleular rearrangements with (approximate) absolute rate constants of 4.6 x 107 and 2.1 x 10' s-l, respectively, at 21'C. Attention is currently focused on the kinetics of intramolecular carbene rearrangements. Laser flash