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Kinetics of the chlorination of secondary amines by N-chlorosuccinimide

✍ Scribed by Juan M. Antelo; Florencio Arce; Julia Franco; Maria C. Garcia Lopez; Maria Sanchez; Angel Varela

Publisher
John Wiley and Sons
Year
1988
Tongue
English
Weight
432 KB
Volume
20
Category
Article
ISSN
0538-8066

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✦ Synopsis

The chlorinations of dimethylamine, diethylamine, methylethanolamine, ethylethanolamine and diethanolamine by N-chlorosuccinimide have been found to be equilibrium reactions of order one with respect to both N-chlorosuccinimide and amine in the forward direction and of order one with respect to succinimide and the resulting N-chloramine in the other. These results are explained by postulating a mechanism in which the rate controlling step consists in direct exchange of positive chlorine between the N-chlorosuccinimide and the amine.

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