Structure—activity considerations in kinetics and mechanism of chlorine exchange between chloramine-T and secondary amines

Chloramine-T in Radiolabeling Techniques

Chloramine-T in Radiolabeling Techniques: I. Kinetics and Mechanism of the Reaction between Chloramine-T and Amino Acids

✍ A.A. Hussain; R. Awad; P.A. Crooks; L.W. Dittert 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 317 KB

The determination of the rate and pH dependency of chlorination of amino acids by chloramine-T (CAT) using the model compounds beta-alanine, L-alanine, and L-alanine ethyl ester was investigated. The reactions were studied under pseudo-first-order conditions where the amino acid concentration was in