Kinetics for reactions of phenoxy radical, C 6 H 5 O, with itself and with O 3 were examined at 298 K and low pressure (1 Torr) using discharge flow coupled with mass spectrometry (DF/MS). The rate constant for the phenoxy radical self-reaction was determined to be k The rate constant for the C 6 H
Kinetics of the C6H5 + O2 Reaction at Low Temperatures
β Scribed by Yu, T.; Lin, M. C.
- Book ID
- 126167077
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 701 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reaction of CzH502 with NO in helium carrier gas at 295 K with [He] = 1.6 X 1017 cm-3 has been studied using a gas flow reactor sampled by a mass spectrometer. Because no parent molecular ion or suitable fragment ion produced by CzH502 could be detected, the reaction was followed by measuring th
The reaction between CzH5 and 0 2 a t 295 K has been studied with a flow reactor sampled by a mass spectrometer. With helium as the carrier gas the rate coefficient was found to increase from (1.2 f 0.3) X cm3/s as [He] was increased from 2 X 10I6 to 3.4 X 1017 The importance of to (3.6 f 0.9) has
Low-temperature experiments on the ion-molecule reaction between NH: and H2 show that this reaction can occur with an appreciable rate at very low temperature ( Q: 100 K) despite the existence of an activation energy barrier. Theoretical calculations have confirmed the mechanism for the process at l