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Kinetics of the boric acid catalyzed decomposition of the N-nitrosohydroxylamine-N-sulfonate ion

โœ Scribed by Switkes, Ellen G.; Dasch, Gregory A.; Ackermann, Martin N.


Book ID
126076213
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
492 KB
Volume
12
Category
Article
ISSN
0020-1669

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A kinetic study of the decomposition reactions of N-bromoalanine, N-bromo-2-aminobutyric acid, and N-bromonorvaline shows them to be first-order with respect to N-bromoaminoacid concentration and independent of both excess aminoacid and pH over the interval pH 9-11. In this pH range the mean rate co