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Kinetics of the aquation of cis-chlorocyanobis(2,2′-bipyridine)cobalt(III) and cis-chlorocyanobis(1,10-phenanthroline)cobalt(III) cations

✍ Scribed by Gaetano Schiavon; Fulvia Marchetti


Book ID
108428768
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
198 KB
Volume
4
Category
Article
ISSN
0277-5387

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Kinetics of the alkaline hydrolysis of c
✍ Sultan I. Amer; John A. McLean Jr. 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 345 KB

The alkaline hydrolysis of cisand rrans-diacetatobis(l,2-propanediamine)cobalt(III) cations appears to follow a substitution nucleophilic unimolecular conjugate base mechanism. In these cations, the acetate ligands are replaced by hydroxide ion in a stepwise manner. Both isomers undergo complete hy