## Abstract It was established that chlorine reacts with both water and hydroxyl ions. At a short reaction time when the pH was less than 3 the reversible reaction of chlorine and water controlled the absorption rate. From pH 3 to 10.5 the forward reaction predominated and yielded an apparent first
Kinetics of the aluminum-chlorine reaction
โ Scribed by Charles Cozewith; Kun Li
- Publisher
- American Institute of Chemical Engineers
- Year
- 1967
- Tongue
- English
- Weight
- 534 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0001-1541
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The reaction kinetics of atomic chlorine with a series of biogenic hydrocarbons, including the two enantiomers of โฃ-pinene, were studied at 298 K and 1 atm pressure using a relative rate technique. The simultaneous losses of the biogenic of interest and a reference compound, either n-nonane or n-but
The process of two-and three-particle photorecombmation of chlorine atoms in a reftected shock wave and in a supersonic nozzle has been studied. The rate constants of photorecombinahon betaeen 960 K and 2800 K have been determmed experimentally for the first time. The contriiu~on of A and B states o
## Abstract For Abstract see ChemInform Abstract in Full Text.
Time resolved UV spectroscopy has been used to investigate the role of acetyl radical in the photolytically initiated chain reaction of acetaldehyde with chlorine. At a resolution of 2 nm, acetyl has a broad, unstructured, absorption in the 200-280 nm range, with a peak cross section of (1.07 + 0.11