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Kinetics of the addition of diethyl phosphonate to various p-substituted benzylideneanilines

✍ Scribed by Lola V. Hopkins; James P. Vacik; William H. Shelver

Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
314 KB
Volume
61
Category
Article
ISSN
0022-3549

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πŸ“œ SIMILAR VOLUMES

Phosphonic systems. Part 15. Addition of
Phosphonic systems. Part 15. Addition of diethyl prop-2-enylphosphonate to aldehydes: Fragmentation vs. isomerization of kinetic products
✍ Elmar L. Muller; Tomasz A. Modro πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 470 KB

## Abstract Lithiated diethyl prop‐2‐enylphosphonate adds to an aliphatic or an aromatic aldehyde, yielding a diastereomeric mixture of the kinetically controlled α‐adduct. Upon warming, these adducts decompose back to starting materials to give finally the thermodynamically controlled γ‐adducts, o