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Kinetics of Silylene Insertion into N−H Bonds and the Mechanism and Kinetics of the Pyrolysis of Dimethylsilylamine

✍ Scribed by O'Neal, H. E.; Ring, M. A.; Martin, J. G.; Navio, M. T.


Book ID
127084701
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
60 KB
Volume
102
Category
Article
ISSN
1089-5639

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Kinetics and mechanism of the pyrolysis
✍ Thomas J. Houser; Teodomiro Cuzcano 📂 Article 📅 1975 🏛 John Wiley and Sons 🌐 English ⚖ 445 KB

## Abstract The rate of the inhibited pyrolysis of pentachloroethane was studiedover the temperature range of 820 to 865°K using the toluene‐carrier technique in a stirred‐flow reactor. The pyrolysis rate was found to be first order in reactant, and the rate constant is described by __k__=10^11.6±0