Kinetics and mechanism of the pyrolysis of allyltrimethylsilane
β Scribed by Barton, T. J.; Burns, S. A.; Davidson, I. M. T.; Ijadi-Maghsoodi, S.; Wood, I. T.
- Book ID
- 126928508
- Publisher
- American Chemical Society
- Year
- 1984
- Tongue
- English
- Weight
- 656 KB
- Volume
- 106
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract The rate of the inhibited pyrolysis of pentachloroethane was studiedover the temperature range of 820 to 865Β°K using the tolueneβcarrier technique in a stirredβflow reactor. The pyrolysis rate was found to be first order in reactant, and the rate constant is described by __k__=10^11.6Β±0
The kinetics of the gas phase pyrolysis of dimethyl sulfide (DMS) was studied in a static system a t 681-723 K by monitoring total pressure-time behavior. Analysis showed the pressure increase to follow DMS loss. The reaction follows two concurrent paths: ## Me2S C2H4 + H2S --% CH, + CHzS with a