The kinetics of Ru(III) catalysed oxidation of neuroleptic drug, gabapentin by diperiodatonickelate(IV) (DPN) in alkaline medium at 298 K and a constant ionic strength of 0.30 mol dm -3 was studied spectrophotometrically. The oxidation products are 1-(hydroxymethyl) cyclohexane acetic acid and Ni(II
Kinetics of ruthenium(III)-catalysed oxidation of paracetamol by diperiodatonickelate(IV) in aqueous alkaline medium (stopped flow technique)
β Scribed by R.M. Mulla; H.M. Gurubasavaraj; S.T. Nandibewoor
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 463 KB
- Volume
- 314
- Category
- Article
- ISSN
- 0926-860X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of oxidation of 1,4-Dioxane (Dio) by Diperiodatonickelate (IV) (DPN) in aqueous alkaline medium at a constant ionic strength of 1.5 mol dm Οͺ3 was studied spectrophotometrically. The reaction shows first-order kinetics in [DPN] and less than unit order dependence each in [Dio] and [OH Οͺ
## Abstract The kinetics of oxidation of vanillin (VAN) by diperiodatocuprate(III) (DPC) in alkaline medium at a constant ionic strength of 0.50 mol dm^β3^ was studied spectrophotometrically. The reaction between DPC and vanillin in alkaline medium exhibits 1:2 stoichiometry (vanillin: DPC). The re