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Kinetics of reactions in solutions under pressure. 52. Effect of pressure on concerted and stepwise sigmatropic shifts

✍ Scribed by Le Noble, W. J.; Daka, M. Rajaona

Book ID
125941344
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
266 KB
Volume
100
Category
Article
ISSN
0002-7863

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✍ GΓ©rard Jenner πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 90 KB πŸ‘ 2 views

The kinetic pressure effect on some Michael-like and [4 2] cycloadditions in aqueous solution was studied. This effect is complex and variable, in contrast to the pressure dependence of rate constants in organic solvents. In order to determine the origin of this kinetic behavior, systematic solvent