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Kinetics of reactions in solutions under pressure. 49. Chlorine kinetic isotope effects in the methylation of pyridine and 2,6-lutidine

✍ Scribed by Le Noble W. J., ; Miller, Arnold R.

Book ID
120971126
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
499 KB
Volume
44
Category
Article
ISSN
0022-3263

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Kinetic isotopic effects (KIE) were measured for oxidation, bromination and selenylation of c-C6Ht2/c-C&i2 in pyridine solution for different Gif-type, Fenton and other systems. The comparison of KIE and relative reactivity data for the pair c-C5Ht&C6Ht2 proved that the mechanism of activatton in Gi