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Kinetics of reaction of dodecacarbonyltriosmium with diphenylacetylene

โœ Scribed by Poe, Anthony J.; Sampson, Clifford N.; Smith, Richard T.


Book ID
120010408
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
729 KB
Volume
108
Category
Article
ISSN
0002-7863

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Homogeneous isomerisation of 1 -pen tene to 2-cisand 2-trans-pentene occurs in presence of dodecacarbonyltriosmium. A contemporaneous formation of compounds of molecular formula H0s3(C0),&H, and HzOs3(CO)&,HS can be observed. The structures of these complexes are discussed. An analogous behaviour is