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Kinetics of radical polymerization—XVII. The effects of charge-transfer complexes on some elementary processes in radical polymerization

✍ Scribed by B. Turcsányi; F. Tüdos; J. Ladik

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
533 KB
Volume
6
Category
Article
ISSN
0014-3057

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✦ Synopsis

The molecular compounds (charge-transfer complexes) which may be formed in some radical polymerizations influence greatly the kinetics of the processes. We have investigated theoretically those factors which determine the parameters of the reactions between radicals and their reaction partners with a closed shell ,r-electron system. Special attention has been paid to the effect of the formation of molecular compounds. We have concluded that the increase of reactivity can be attributed to the increase in the resonance energy of the transition state. On this basis, some anomalous effects in inhibited polymerizations and in copolymerizations can be satisfactorily interpreted.

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