The effect of aromatic nitro compounds (s-trinitrobenzene, o-and p-dinitrobenzene) was studied on the polymerization of p-methyl styrene by dilatometric method, using AIBN initiator at 50°C. The value of the stoichiometric coefficient 01) and of the relative reactivity (kJ&) was determined. In bulk
Kinetics of radical polymerization, LVI. Investigation of the effect of molecular inhibitors on the radical polymerization of p-methyl-styrene. c-nitroso compounds
✍ Scribed by Ida Gyöngyhalmi; Tamara Földes-Berezsnich; Ferenc Tüdős
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 209 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0014-3057
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brief report is given of the method of intermittent illumination and of the rotating sector polymerization instrument built in our laboratory. The solvent dependence of chain propagation and termination rate constants was investigated for the polymerization system styrene-benzene at 50. The observed
Molecular mass distribution was investigated for the polymerization of styrene initiated by AIBN at 50 in the presence of various solvents. Two types of solvents were chosen; in one, there is no chain transfer to solvent (Bz, DMF) whereas in CC14 the chain transfer should be considered. The molecula
## Abstract The grafting through method was employed to study the effect of nanoclay confinement on the atom transfer radical polymerization (ATRP) of styrene. An ammonium salt containing a double bond on its structure was used as a clay modifier. Employing ATRP to polymerize styrene in the presenc