Kinetics of radical polymerization of tetrafunctional monomers with intramolecular cyclization: A computer simulation study
β Scribed by I.I. Romantsova; O.V. Pavlova; S.M. Kireyeva; Yu.M. Sivergin
- Book ID
- 116048434
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 474 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0032-3950
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## Abstract The free radical polymerization kinetics of the isomer sodium salts of __o__β and __p__βmethacryloylaminophenylarsonate in aqueous solution have been studied using a dilatometric method. The polymerizations, initiated with potassium persulfate, were carried out at a constant monomer ini
Ab initio calculations have been used to characterize the transition states for halogen abstraction by CH 3 in reactions with CF 4 , CF 3 Cl, CF 3 Br, and CF 3 I (1-4). Geometries and frequencies were obtained at the HF/6-31G(d) and levels of theory. En-MP2 Ο full/6-31G(d) ergy barriers were compute