𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics of styrene emulsion polymerization with a stable monomer radical

✍ Scribed by Morton Litt

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
378 KB
Volume
30
Category
Article
ISSN
0959-8103

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Stable Free Radical Polymerization in Em
Stable Free Radical Polymerization in Emulsion: Modeling the Thermodynamics of Monomer Transfer between Droplets and Particles
✍ Jordan Pohn; Catherine Buragina; Michael K. Georges; Barkev Keoshkerian; M. F. C πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 229 KB

## Abstract A mathematical model is developed from polymer solution thermodynamics and stable free radical polymerization kinetics to predict the monomer swelling behavior of large droplets and small particles that coexist during the seeded polymerization of styrene in emulsion. This model is used

Stable Free-Radical Polymerization of St
Stable Free-Radical Polymerization of Styrene in Combination with 2-Vinylnaphthalene Initiation
✍ Jeremy R. Lizotte; Timothy E. Long πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 124 KB

## Abstract The elevated temperatures required for the stable free‐radical polymerization (SFRP) process lead to thermal initiation of styrene via the classic Mayo mechanism. Studies have shown the utility of styrene thermal initiation in controlled autopolymerization processes. In addition, the th

Emulsion polymerization of styrene using
Emulsion polymerization of styrene using reaction calorimeter. III. Effect of initial monomer/water ratio
✍ L. Varela De La Rosa; E. D. Sudol; M. S. El-Aasser; A. Klein πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 407 KB πŸ‘ 2 views

The batch emulsion polymerization of styrene was studied as a function of the initial monomer charge. The emulsifier (sodium lauryl sulfate) concentration was fixed at a level in excess of its critical micelle concentration (cmc). The mechanism of the polymerization was examined through data obtaine

On the kinetics of styrene emulsion poly
On the kinetics of styrene emulsion polymerization above CMC. I. A mathematical model
✍ Jorge Herrera-OrdΓ³Γ±ez; Roberto Olayo πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 266 KB πŸ‘ 2 views

A detailed mathematical model of the kinetics of styrene emulsion polymerization has been proposed. Its main features/assumptions are compartmentalization, micellar and homogeneous nucleation, particle formation by both initiator-derived and desorbed radicals, dependence on the particle size of the

On the kinetics of styrene emulsion poly
On the kinetics of styrene emulsion polymerization above CMC. II. Comparison with experimental results
✍ Jorge Herrera-OrdΓ³Γ±ez; Roberto Olayo πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 254 KB πŸ‘ 2 views

The results of a detailed mathematical model developed in part I of this series (J Polym Sci A: Polym Chem 2000, 38, 2201) are discussed and compared against experimental data. The model results, which were obtained without the coagulation of the particles being taken into account, are congruent wit