Kinetics of polymerization of styrene initiated by substituted benzoyl peroxides. I. Effect of thermal initiation
β Scribed by O'Driscoll, Kenneth F. ;White, Paul J.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1963
- Tongue
- English
- Weight
- 106 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0449-2986
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π SIMILAR VOLUMES
## Abstract The rate and degree of bulk polymerization of styrene and vinyl acetate initiated by difuroyl peroxide and, for comparison, by dilauroyl and dibenzoyl peroxides were measured at several temperatures as a function of the initiator concentration. Also the rates of initiation were determin
The initiation of some substituted styrenes by butyl lithium has been studied. In hydrocarbon solvents the rates are given byRi ~k [M][BuLi] n where n lies between ΒΌ and ~ for benzene solutions and is approximately 0.57 for n-hexane solution. In benzene solution the relative rates of initiation of t