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Kinetics of Photoresponse of the Chlorine Dioxide-Iodine-Malonic Acid Reaction

✍ Scribed by Horváth, Attila K.; Dolnik, Milos; Zhabotinsky, Anatol M.; Epstein, Irving R.

Book ID
126919086
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
65 KB
Volume
104
Category
Article
ISSN
1089-5639

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Equilibrium, kinetics, and mechanism of
Equilibrium, kinetics, and mechanism of the malonic acid–iodine reaction
✍ Kenneth R. Leopold; Albert Haim 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 615 KB

The equilibrium constant for the reaction CH,(COOH), + I J -@ CHI(CO0H)Z + 21-+ H+, measured spectrophotometrically at 25OC and ionic strength 1.00M (NaC104), is (2.79 f 0.48) X 10-'M2. Stopped-flow kinetic measurements a t 25OC and ionic strength 1.OOM with [H+] = (2.09-95.0) X lO-3M and [I-] = (1.