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Kinetics of oxidation-reduction destruction of trisdipyridylruthenium (III) in weakly alkaline and weakly acidic media

✍ Scribed by O. V. Gerasimov; G. L. Elizarova; V. N. Parmon


Book ID
112449138
Publisher
Springer
Year
1988
Tongue
English
Weight
464 KB
Volume
37
Category
Article
ISSN
1573-9171

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Kinetics and mechanism of oxidation of i
✍ Ritam Mukherjee; Basab Bijayi Dhar; Rupendranath Banerjee πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 114 KB

## Abstract The complex ion [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)~2~]^4+^ (1) (phen = 1,10‐phenanthroline) and its hydrolytic derivatives [Fe^III^~2~(μ‐O)(phen)~4~(H~2~O)(OH)]^3+^ (1a) and [Fe^III^~2~(μ‐O)(phen)~4~‐ (OH)~2~]^2+^ (2a) coexist in rapid equilibria in the range pH 4.23–5.35 in the presence