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Kinetics of oxidation of vanadium(IV) by alkyl hydroperoxides in acidic, aqueous solution

✍ Scribed by Ma, Rong; Bakac, Andreja; Espenson, James H.


Book ID
127225989
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
849 KB
Volume
31
Category
Article
ISSN
0020-1669

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Kinetics and mechanism of oxidation of b
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## Abstract The reaction between benzohydrazide and potassium bromate catalyzed by vanadium(IV) was studied under pseudo‐first‐order condition keeping large excess of hydrazide concentration over that of the oxidant. The initiation of the reaction occurs through oxidation of the catalyst vanadium(I