The kinetics of the permanganate oxidation of formic acid in aqueous perchloric acid a t 30°C were examined by the spectrophotometric method. The chemical reaction 2Mn0, A BHCOOH + 2H + -2Mn02 + 3C0, + 4H20. appears to proceed via several parallel reactions. The overall rate equation has been obtain
On the kinetics of the oxidation of formic acid by vanadium(IV) in aqueous solution
✍ Scribed by Börje Folkesson; Ragnar Larsson
- Book ID
- 108324523
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 578 KB
- Volume
- 162
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reaction between formic acid and bromine in strongly acid aqueous media at 298 K Brz + HCOOH -2 Br-+ 2 H+ + COz was studied by absorption spectrophotometry (A = 447 nm). Reaction rates, expressed as H = -d[Brz]/dt, depend on the concentrations of HCOOH (0.3-2.4M), Br2[(2.7-13.6) X 10-3M], H+ (0.
## Abstract The reaction between benzohydrazide and potassium bromate catalyzed by vanadium(IV) was studied under pseudo‐first‐order condition keeping large excess of hydrazide concentration over that of the oxidant. The initiation of the reaction occurs through oxidation of the catalyst vanadium(I