Kinetics of oxidation of monohydric aliphatic alcohols by ozone
โ Scribed by V. V. Shereshovets; F. A. Galieva; I. R. Akhunov; V. D. Komissarov; A. V. Tsar'kov; I. Kh. Bikbulatov
- Book ID
- 112446251
- Publisher
- Springer
- Year
- 1983
- Tongue
- English
- Weight
- 319 KB
- Volume
- 32
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract Kinetic parameters of the reaction of ozone with aliphatic alcohols of different structures are obtained. The ratio between the relative reactivities of the primary: secondary: tertiary alcohols was found to be 1:15:138. The bond energy changes in the same sense as the activation energy
The oxidation of some aliphatic alcohols by quinolinium fluorochromate (QFC) in dimethyl sulfoxide leads to the formation of corresponding carbonyl compounds. The reaction is first order with respect to QFC. The reaction exhibited Michaelis-Menten type kinetics with respect to the alcohol. The react