The temperature dependency of the rate constants for the gas phase reaction of OH radicals with a series of chloroalkanes was measured in the temperature range from 295 to 360 K at a total pressure of I atm. The rate constants were obtained by using the absolute technique of pulse radiolysis combine
Kinetics of OH Radical Reactions with Methane in the Temperature Range 295−660 K and with Dimethyl Ether and Methyl- tert -butyl Ether in the Temperature Range 295−618 K
✍ Scribed by Bonard, Amélie; Daële, Véronique; Delfau, Jean-Louis; Vovelle, Christian
- Book ID
- 126298380
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 114 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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Rate constants for the reactions of OH radicals with CH,CHF, and CHCI,CF, have been determined over the temperature range 295-388 K and a total pressure of 1 atm. The OH rate data were obtained using the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy.
Absolute rate coefficients for the reaction of CN radicals with methane (k,), ethane (kz) and propane ( kJ) were measured as a function of temperature in a heatable quartz reactor by means of a laser photolysis/laser-induced fluorescence (LP/LIF) technique. CN was generated by 193 nm photolysis of c
Absolute rate coefikients for the reaction of NC0 radicals with NO were measured in the temperature range between 294 and 1260 K and the pressure range between 6 and 170 Torr in a heatable quartz reactor by means of the laser photolysis/laser-induced fluorescence technique. NC0 radicals were produce