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Kinetics of isotopic exchange between gaseous hydrogen and the hydrogen dissolved in palladium

โœ Scribed by B.M. Andrey'yev; G.K. Bor'yeskov; Chjen-Chan-Tzun; V.M. Tzeeonsky


Book ID
113173120
Publisher
Elsevier Science
Year
1967
Tongue
English
Weight
98 KB
Volume
7
Category
Article
ISSN
0021-9517

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Hydrogen isotope exchange between pentaf
โœ A. K. Nayak; S. K. Sarkar ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 140 KB

It is shown experimentally that pentafluoroethane undergoes rapid protium-deuterium exchange with water in the presence of hydroxide ion. Addition of dimethylsulfoxide enhances the rate at least by a factor of 100. The first measured fractionation factor data are presented for the temperature range