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Kinetic isotope effect in hydrogen isotope exchange between diphenylphosphine and hexylamine in aprotic solvents

โœ Scribed by Andrzej Wawer; Iwona Wawer


Book ID
103594338
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
515 KB
Volume
54
Category
Article
ISSN
0167-7322

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Lack of kinetic hydrogen isotope effect
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Second order rate constants for C2H2 or C2D2 polymerizations into vinylacetylene and higher C,H, products have been measured in a static reactor by dynamic mass spectrometry between"770-980 K. They are nearly identical within experimental error (-+50%). It is shown that these results are consistent