Kinetics of CN(X 2Σ+) radical reactions with HCN, BrCN and CH3CN
✍ Scribed by S. Zabarnick; M.C. Lin
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 618 KB
- Volume
- 134
- Category
- Article
- ISSN
- 0301-0104
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Absolute rate constants were measured for the reaction CN + CH20 over the temperature range 297-673 K and CN + 1,3,5-trioxane over the range of 297-600 K by the laser photolysis/laser induced fluorescence technique. The rate constants for these reactions can be effectively represented, in units of c
Spectrophotometric methods have been used to obtain rate laws and rate parameters for the following reactions: with k,, kb, E,, Eb having the values 85 f 5 l./mole.s, 5.7 f 0.2 s-l (both at 298.2'K), and 56 f 4 and 66 f 2 kJ/mole, respectively. (2) with k, = 0.106 f 0.004 I./mole .s at 298.2'K and