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Kinetics of CN(X 2Σ+) radical reactions with HCN, BrCN and CH3CN

✍ Scribed by S. Zabarnick; M.C. Lin


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
618 KB
Volume
134
Category
Article
ISSN
0301-0104

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Spectrophotometric methods have been used to obtain rate laws and rate parameters for the following reactions: with k,, kb, E,, Eb having the values 85 f 5 l./mole.s, 5.7 f 0.2 s-l (both at 298.2'K), and 56 f 4 and 66 f 2 kJ/mole, respectively. (2) with k, = 0.106 f 0.004 I./mole .s at 298.2'K and