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Kinetics of chlorination of zirconia in mixture with petroleum coke by chlorine gas

✍ Scribed by P. K. Jena; E. A. Brocchi; M. L. Dos Reis

Book ID
107452321
Publisher
The Minerals, Metals & Materials Society
Year
1999
Tongue
English
Weight
176 KB
Volume
30
Category
Article
ISSN
1543-1916

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The production o f C l 0 0 and C10 radicals following the flash photolysis of chlorine + oxygen mixtures has been studied. For the mechanism the following kinetic parameters were measured: and k:,/c(C100; 250 nm) = 9.7 x 105 cm/sec. Then h:3 = 5.9 X lo9 l/mol.sec, h2 = 1.0 X 10" limol-sec, and t(C