The kinetics of the ethane pyrolysis have been studied at temperatures from 550 to 596'C and with 0 to 620,; of added nitric oxide. The rates of production of various products were studied by gas chromatography; ethylene, hydrogen, methane, nitrogen, water, nitrous oxide and acetonitrile were found
Kinetics of cellulose pyrolysis in the presence of nitric oxide
β Scribed by Stuart Cooley; Michael J. Antal Jr.
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 624 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0165-2370
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Although our pyrolytic studies of five alkyl nitrites (RONO) have shown that it is possible to determine precise, acceptable values for k 1: (0 RONO -RO + NO we have been uncertain about the mechanism for the first order production of nitroxyl from primary and secondary nitrites. Nitroxyl could ari
The recombination of iodine atoms following the flash photolysis of iodine in the presence of nitric oxide is interpreted through the mechanism ki k-i with k~ = 3.5 X lo9 1.2/rno12-sec; kz = 1 X 10" l./rnol.sec; k3 = 2.1 X LO7 l./mol-sec at 298Β°K; E3 = 11 kJ/ rnol; and AH"] = 76 f 6 kJ/mol. Lower a